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Researchers Realize Copper-catalyzed Asymmetric Nucleophilic Ring-opening Reaction of Tetrasubstituted Cyclopropanes to Prepare α-Tertiary Amines

Researchers Realize Copper-catalyzed Asymmetric Nucleophilic Ring-openin...[ 12, 2025]
In principle, the reaction of 1,1,2,2-tetrasubstituted donor-acceptor cyclopropanes ( DACs ) produces tetrasubstituted stereocenters, which is of great significance for the synthesis of related complex functional molecules. However, desp...

Upconverted Circularly Polarized Luminescence Realized on Chiral Lanthanide-organic Tetrahedral Complexes

Upconverted Circularly Polarized Luminescence Realized on Chiral Lanthan...[ 11, 2025]
Integrating circularly polarized luminescence with upconversion has garnered considerable attention. Upconverted circularly polarized luminescence (UCCPL) represents a novel anti-Stokes-like chiropticalbehavior that converts unpolarized ...

Researchers Design Low-stagnation Model-free Predictive Current Control of PMSM Drives

Researchers Design Low-stagnation Model-free Predictive Current Control ...[ 23, 2025]
Model-free predictive control (MFPC) is an essential robustness control strategy for motor drives. However, due to the impact of stagnation and its negative effects, the accuracy of the adopted data-driven model fails to represent the mo...

Efficient and Selective Oxidation of Anilines and Sulfides Achieved by Integrating Cationic Frameworks, Strong Lewis Acidic sites, and Brønsted Acidic Hydroxyl Groups into Microenvironments

Efficient and Selective Oxidation of Anilines and Sulfides Achieved by I...[ 22, 2025]
In nature, organic reactions are predominantly catalyzed by enzymes, which demonstrate remarkable efficiency and exceptional selectivity. For decades, researchers have focused on designing structures to replicate enzymatic catalytic proc...

In Situ Integration of Metallic Catalytic Sites and Photosensitive Centers within Covalent Organic Frameworks Designed for Enhanced Photocatalytic Reduction of CO2

In Situ Integration of Metallic Catalytic Sites and Photosensitive Cente...[ 21, 2025]
Covalent organic frameworks (COFs) are a promising platform for heterogeneous photocatalysis due to their stability and design diversity, but their potential is often restricted by unmanageable targeted excitation and charge transfer.Mos...

Researchers Realize Photoswitchable Topological Regulation of Covalent Macrocycles, Molecular Recognition, and Interlocked Structures

Researchers Realize Photoswitchable Topological Regulation of Covalent M...[ 16, 2025]
Dynamic covalent macrocycles, known for their reversible bond formation and adaptability, have presented challenges in achieving precise topological control. By leveraging photoswitches, this work demonstrated the light-controlled bidire...

In situ Establishment of Rapid Lithium-ion Transport Pathways Enables Dendrite-free and Long-lifespan Solid-state Lithium Batteries

In situ Establishment of Rapid Lithium-ion Transport Pathways Enables De...[ 15, 2025]
Solid-state lithium-ion batteries are considered a key development direction for the next generation of lithium-ion batteries due to their high energy density, durable cycling performance, and high safety. The development of solid-state ...

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